Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

Hypo‐elastic and hyper‐elastic equations of soils          下载免费PDF全文

Koichi Hashiguchi 《国际地质力学数值与分析法杂志》2018,42(13):1554-1564

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基于SPEI的渭河流域干旱时空变化特征分析          下载免费PDF全文

邹磊  余江游  夏军  王飞宇 《干旱区地理》2020,43(2):329-338

以标准化降水蒸散指数（SPEI）作为评估指标，基于渭河流域28个气象站点1961—2017年实测降水量和气温数据，采用Mann-Kendall（M-K）趋势检验、经验正交函数以及小波变换等方法分析渭河流域干旱时空变化特征，并研究渭河流域干旱与6种大尺度气候因子之间的相关关系，进一步探讨主要气候因子对流域干旱时空分布特征的潜在影响。研究表明：渭河流域在1961—2017年间整体呈现出变旱的趋势。通过经验正交函数分解，渭河流域干旱分布场主要有3种典型模态类型，分别为全局型、西北—东南反向分布型以及东—西反向分布型；同时，大尺度气候因子南方涛动指数SOI与流域干旱分布场具有更好的相关关系，对该区域内干旱变化有较强的影响。  相似文献   

社会网络视角中世界文化遗产地旅游村寨的利益关系治理     

时少华  李享 《热带地理》2020,40(4):625-635

以云南省红河州元阳县哈尼梯田核心区域2个典型的旅游村寨（大鱼塘村和普高老寨）为例，对两村寨利益相关者从网络凝聚性、网络互惠性、网络核心边缘、网络传递性、网络经纪人等5个方面展开关系数据分析，结果显示：1）大鱼塘村压力集团内部、压力集团与社区、企业与政府之间的利益关联性和联系的紧密性不足；2）两村当地政府和压力集团与社区之间的互惠性低于整体平均互惠性；3）两村利益网络中边缘结构较核心结构更加明显，这导致了利益关系的不平衡；4）两村当地政府利益集团传递性相对较低，当地社区传递性最高；5）两村中利益集团间缺少部分协调人、守门人、代理人、联络人等角色。最后提出相应建议：1）提升哈尼梯田利益关系由弱利益关系转变为强利益关系，改变利益集团间核心边缘利益关系格局；2）进一步加强各利益集团内部及之间的关联性；3）加强以企业和政府机构为顶点的组间利益传递，让利益流动逐步打破哈尼梯田利益集团之间的核心边缘关系结构；4）重点加强社区在利益关系网络中的参与机会与权力，对社区进行增权；5）利益集团内部要重点培育协调人和顾问角色，利益集团之间要重点培育企业与政府、社区、压力集团之间的守门人、代理人和联络人角色，以及社区与政府和企业之间的守门人、代理人角色。  相似文献   

新冠肺炎疫情扩散与人口流动的空间关系及对中国城市公共卫生分类治理启示     

向云波  王圣云 《热带地理》2020,40(3):408-421

人口流动影响新冠肺炎疫情传播与风险扩散。基于百度迁徙大数据和各省市区卫生健康委员会数据，结合地理信息技术，研究了2020年1月1日至3月5日136个城市新冠肺炎疫情扩散与武汉市人口流出的空间关系及其对我国城市公共卫生治理启示。研究表明：1）中国新冠肺炎疫情扩散过程具有阶段性特征，经历了疫情发生与隐性扩散、快速扩散与暴发、扩散遏制和扩散衰减4个阶段。2）研究时间段武汉市人口主要流向湖北省境内以及周边省市和北京、上海、广州、深圳等一线城市，具有地理邻近性和倾向区域中心城市的人口流入特征。受地理距离、时间成本、社会经济联系、境外输入等因素的影响，新冠肺炎疫情空间分布的不平衡性明显，长江中游城市群、京津冀城市群、长三角城市群、粤港澳大湾区和成渝城市群成为新冠肺炎疫情集中分布的重点区域，一些重点出入境口岸城市的新冠疫情扩散风险较大。3）新冠肺炎疫情扩散与人口流出之间具有较强的正向等级相关性。两者之间的空间关系可以分为8种调控类型，近90%的城市具有人口流入多、确诊病例数高或人口流入少、确诊病例数低的特征。其中，人口流入多、确诊病例数高的城市主要集中分布在湖北省境内以及中国重点城市群的中心城市，其防控压力来自人口流入多、确诊病例数高带来的疫情扩散风险；而人口流入少、确诊病例数低的城市分布较为分散，其防控的难点在于提高防控对策的精准性。我国疫情防控取得了显著成效，但随着时间的演进全球疫情形势反弹的不确定性仍然存在，外防输入、内防反弹的压力依然很重，现阶段乃至未来一段时期，疫情防控将伴随中国经济社会发展成为新常态。建议针对8种调控类型，从人口流动、交通和资源等引导与管控方面分类提出精细化的疫情防控策略，提升城市公共卫生治理能力。  相似文献   

地方政府土地出让干预对区域工业碳排放影响的对比分析——以中国8大经济区为例     

王博  吴天航  冯淑怡 《地理科学进展》2020,39(9):1436-1446

探讨不同区域地方政府干预对碳排放的影响差异,对于中国推进碳减排战略、协调区域经济社会发展具有重要意义。鉴于此,论文基于地方政府土地出让的视阈,以中国8大经济区为研究对象,有机耦合STIRPAT模型与CKC模型,构建形成STIRPAT拓展模型,并使用2007—2016年中国28个省(市、自治区)的工业面板数据,对比考察8大经济区政府土地出让干预对区域碳排放的影响差异。结果表明:不同经济区的地方政府土地出让干预对区域碳排放的影响存在显著差异。其中,同为CKC“倒N”型的北部沿海、南部沿海、长江中游经济区,其政府土地出让干预对区域碳排放的影响呈现出北部沿海经济区为负、南部沿海经济区为正、长江中游经济区无显著影响的差异效果;同为CKC“倒U”型的东北、西南和西北经济区,其政府土地出让干预对区域碳排放的影响,东北和西南经济区都显著为负,西北经济区未表现出显著影响;同为CKC“U”型的东部沿海和黄河中游经济区,其政府土地出让干预对碳排放也呈现出前者为负、后者为正的相反影响。研究结果可为制定碳减排差别化政策、协调区域可持续发展提供参考。  相似文献   

Correspondence between the large volcanic eruptions and ENSO events over AD 1525–2000     

Fang  Xiuqi  Zheng  Xue  Zhang  Xing 《地理学报(英文版)》2020,30(1):103-118

ENSO is an interannual mode which may be affected by external forcing, such as volcanic eruptions. Based on the reconstructed volcanic eruptions chronology and ENSO sequences, both 195 large volcanic eruptions(VEI≥4) and 398 ENSO(El Ni?o and La Ni?a) events were extracted from 1525 to 2000. An analysis of the correspondence between the large volcanic eruptions and ENSO events was performed by matching the large volcanic eruptions with the types and magnitudes of ENSO events present in the 0–2 years after the eruptions. The results show the following:(1) The percentages of ENSO events within the 3 years after the large eruptions had increased to 68.3% from 31.7% compared with those with no-eruptions in the previous 0–2 years. In addition, the ratio of El Ni?o to La Ni?a events turned from 2:3 to 1:1, and more El Ni?o events occurred in the 0 year after eruptions in the low-latitudes of the Northern Hemisphere and in the tropics but more La Ni?a events occurred in the 0 year after in the high-latitudes of the Northern Hemisphere and the Southern Hemisphere.(2) After the eruptions, the weak(W) El Ni?o events had increased by 8 percentage points and the very strong(VS) El Ni?o events had decreased by 10 percentage points; conversely, there was a decrease by 15 percentage points of the weak La Ni?a events and an increase by 11.4 percentage points of the very strong La Ni?a events. Specifically, the percentages of strong La Ni?a events increased to a peak at 1(+1) year after the eruptions.(3) The percentage of eruptions followed by single-year ENSO was the greatest. The percentage of ENSO events that occurred in the consecutive 2 years following an eruption was approximately equal to the percentage of events that occurred consecutively 3 years following an eruption, and both sets of ENSO magnitudes showed a decreasing trend.  相似文献   

A land-use mix allocation model considering adjacency,intensity, and proximity     

Sunyong Eom  Tsutomu Suzuki  Myeong-Hun Lee 《International journal of geographical information science》2020,34(5):899-923

ABSTRACT

Land-Use Mix (LUM) refers to the strategy of integrating complementary functions within a building or area. While LUM has become a dominant approach in urban planning, its actual benefits and vision for spatial planning remain unclear. To clarify this issue, this study discerns the spatial features of land-use patterns depending on the compatibilities among land-use categories. Accordingly, this study introduces three LUM measures – adjacency, intensity, and proximity – to identify differences in the spatial distribution of land-use categories. Based on these measures, a land-use allocation model is developed to specify spatial patterns satisfying the given compatibilities. This model is tested by applying the concept of the neighborhood unit on a case study of normative land-use patterns subject to specified compatibilities. The results describe spatial features of four compatibility sets, including a set exhibiting a compatibility conflict between the same land-use pair and LUM measures when, for example, a given land-use pair is compatible in terms of intensity but incompatible in terms of proximity. Understanding the spatial features of a normative land-use pattern that satisfies various possible compatibilities will facilitate the incorporation of the LUM approach into local planning guidance and zoning ordinances.  相似文献   

生物土壤结皮铁代谢微生物组成及其功能基因对演替的响应     

王岩松  刘玉冰  王增如  赵丽娜  漆婧华  张雯莉 《中国沙漠》2020,40(3):193-200

采用微生物宏基因组学微阵列GeoChip 5.0技术，选择腾格里沙漠东南缘沙坡头地区不同年代人工固沙植被区的生物土壤结皮（BSC）为对象，分析BSC演替过程中参与铁代谢的功能微生物组成及其功能基因变化特征，研究微生物铁代谢对BSC演替的响应及调控。结果表明：真菌参与铁吸收和转运过程，古菌参与铁转运和贮存过程，细菌则在铁代谢吸收、转运和贮存过程中均起主要调控作用。门水平上，BSC铁代谢功能微生物组成变化对演替的响应不敏感，BSC铁代谢微生物主要为变形菌门（Proteobacteria）。BSC铁代谢功能基因多样性的显著提高和三类铁代谢过程基因信号强度达到最高水平需要经过61 a的演替。调控BSC铁吸收过程的主要功能基因为亚铁氧化酶编码基因iro；调控原核生物铁转运过程的主要功能基因，为羟基苯甲酰丝氨酸铁外膜转运体编码基因cirA和Fe（Ⅱ）转运蛋白编码基因feoB，真菌铁转运过程主要依靠含铁细胞转运体和铁氧化酶高亲和力的作用；调控铁贮存过程的主要功能基因为固定相类核蛋白编码基因dps。在BSC演替阶段末期，上述铁代谢功能基因强度的显著增加促进了微生物的铁代谢潜能。干旱、半干旱荒漠生态系统植被恢复过程中微生物铁代谢潜能的恢复需要较长时间。  相似文献   

不同发展模式下资源环境承载力评价——以海南省为例     

牛方曲  杨欣雨  孙东琪 《热带地理》2020,40(6):1109-1116

文章关注于产业、人口与资源环境要素的作用关系，建构了资源环境承载力综合评价框架，并以海南省为案例区开展应用研究。该框架首先对区域产业重要性进行评价并分级，为产业结构调整提供依据；其次解析了区域产业、人口资源消耗与污染排放强度，最后，基于产业评价结果设定不同的产业结构调整情景，结合产业和人口的资源消耗与污染排放强度评价不同产业结构下的资源环境承载力，即产业和人口的规模上限。结果表明：2016年海南省的经济规模并未超载，产业有进一步发展空间。其中土地资源成为海南省发展的首要限制因素，其次是水环境；海南经济效益较高的支柱产业和基础性产业多为高耗水、高污染的产业，亟需加强水资源的集约利用，并降低污染排放强度。为提升经济发展规模上限，需要培育低能耗、低排放的产业。文章建构的资源环境承载力评价方法将产业、人口与资源环境相联系，其评价结果政策意义更为明确，可为优化产业结构调整、控制产业及人口发展规模提供决策参考。  相似文献